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  • The energy it takes to make biodiesel

    Evening all,

    Here's an electricity load profile of my house today while I made a batch of bio from 180L of WVO.

    I try to get the whole operation as close to the middle of the day as I can while my 1.5 kW solar PV system is doing it's best.

    As you can see, the PV barely touches the sides when the 2.4 kW oil heater is on, but it covers a lot of the mixer, which I run for 90 minutes to do the reaction.

    I think it costs about $0.35/litre to make including KOH and methanol, without the solar contribution.

    Even though the PV system is relatively small, on average, I export 65% of the power it generates to the grid, even though I set my washing machine and dishwasher to go off either side of midday. Quite tough to utilise the full potential of your PV system without a battery.

    Click image for larger version

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    3DB
    1995 Holden (Isuzu) Rodeo 2.8TD 4X4 - B100 since April 2013
    1976 Mercedes 300D Turbo 'The Coal Grenade' - B100 since May 2016 - SOLD
    1994 Peugeot 405 SRDT 1.9L intercooled turbo diesel (Shitbox Rally car.) - B100 since August 2019 - SOLD
    @thirddegreeburns on Instagram
    @thirddegreeburns2019 on Facebook


  • #2
    Re: The energy it takes to make biodiesel

    Reduce the heating and increase the mixing time. Some people make biodiesel at 30°C and agitate (stirrer) for one hour to produce usable biodiesel.
    Life is a journey, with problems to solve, lessons to learn, but most of all, experiences to enjoy.

    Current Vehicles in stable:
    '06 Musso Sports 4X4 Manual Crew Cab tray back.
    '04 Rexton 4X4 Automatic SUV
    '2014 Toyota Prius (on ULP) - Wife's car

    Previous Vehicles:
    '90 Mazda Capella. (2000 - 2003) My first Fatmobile. Converted to fun on veggie oil with a 2 tank setup.
    '80 Mercedes 300D. 2 tank conversion [Sold]
    '84 Mercedes 300D. 1 tank, no conversion. Replaced engine with rebuilt OM617A turbodiesel engine. Finally had good power. Engine donor for W123 coupe. (body parted out and carcass sold for scrap.)
    '85 Mercedes Benz W123 300CD Turbodiesel
    '99 Mercedes W202 C250 Turbodiesel (my darling Wife's car)[sold]
    '98 Mercedes W202 C250 Turbodiesel (my car)[sold]
    '06 Musso Sports Crew Cab well body. [Head gasket blew!]
    '04 Rexton SUV 2.9L Turbodiesel same as Musso - Our Family car.
    '06 Musso sports Crew Cab Trayback - My hack (no air cond, no heater).

    Searching the Biofuels Forum using Google
    Adding images and/or documents to your posts

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    • #3
      Re: The energy it takes to make biodiesel

      3DB, your cost is massive, it equates to 20pence/litre in our money. Last time I worked this out for me it came to well under 10ppl (something like 8.5 from memory)

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      • #4
        Re: The energy it takes to make biodiesel

        Hi 3DB,
        It looks like you are using a 2.4kw heater and heat for about 2 hours.
        Where I live general use home electricity is about 26¢ per kwh.
        That works out to a total cost of about $1.25 to heat the whole batch of oil.
        About 0.7¢ per litre

        Your graph also clearly shows why you should only boil water once
        tillyfromparadise
        Senior Member
        Last edited by tillyfromparadise; 22 September 2017, 08:23 AM.

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        • #5
          Re: The energy it takes to make biodiesel

          Hi all,

          Here is some detail around my cost calculation. It came out to $0.34/litre of finished fuel. This includes chemicals and electricity for all heaters and pumps (net after solar contribution). My starting 180L of WVO is free.

          If I added my time to the calculation, it would be more like $34/litre! As I always say, it is a labour of love rather than a money-saving exercise.

          Tony - I have reduced my start temp from 60C to 50C already to avoid excessive vaporisation of methanol. I mix for 90 min at present - do you think that is an overkill? I am keen to try 30C next batch.

          Cheers,
          Click image for larger version

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          3DB
          1995 Holden (Isuzu) Rodeo 2.8TD 4X4 - B100 since April 2013
          1976 Mercedes 300D Turbo 'The Coal Grenade' - B100 since May 2016 - SOLD
          1994 Peugeot 405 SRDT 1.9L intercooled turbo diesel (Shitbox Rally car.) - B100 since August 2019 - SOLD
          @thirddegreeburns on Instagram
          @thirddegreeburns2019 on Facebook

          Comment


          • #6
            Re: The energy it takes to make biodiesel

            My largest saving when processing is on chemicals. My glycerol pre-treated oil shows a conversion of aroung 20% to start with, so at the moment I am only using around 11.5% added methanol plus a small amount contained in the ASM for full conversion.

            Here are my costings for a 200 litre batch;

            Total electricity used (including that to power my 1/2HP compressor to mix up glyc/oil in the prewash tank) 12KWH @ 14p/KWH £1.60
            (I also do stage 1 conversion at ambient)

            Methanol used 23 litres @ 39 pence/litre. £8.40

            650gms KOH £1.20

            1.2 litres ASM @ £2.00/litre = £2.40

            In total this gives £13.60 which equates to 6.8pence/litre 0.116 Aus Dollars?

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            • #7
              Re: The energy it takes to make biodiesel

              Hi everyone,

              Originally posted by smithy View Post
              My largest saving when processing is on chemicals. My glycerol pre-treated oil shows a conversion of aroung 20% to start with, so at the moment I am only using around 11.5% added methanol plus a small amount contained in the ASM for full conversion.
              Because smithy is relatively new to this forum it is best to explain what smithy means here.
              Apparently people give smithy their drained glycerol that contains large quantities of methanol and KOH which he uses to perform a first stage reaction which he does not call the first stage reaction but instead calls a glycerol pre-treatment. Apparently smithy heats this first stage reaction.

              He then performs a second stage reaction which he calls the first stage reaction that requires he add a further 11%- 12% methanol that he has purchased to achieve a complete reaction. Evidently he does not heat the second stage reaction.
              It is frequently quite confusing to understand what smithy means because he uses different terminology than most people and sometimes omits telling people some of the production steps he performs. You are often not quite sure what he means.

              If people were not giving smithy all their methanol rich glycerol to perform his first stage reaction with, he would have a further expense to supply this methanol other people are apparently giving him.
              tillyfromparadise
              Senior Member
              Last edited by tillyfromparadise; 22 September 2017, 11:53 PM.

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              • #8
                Re: The energy it takes to make biodiesel

                Maybe you should try a glyc wash Tilly, to reduce your costs. BTW my glyc wash is also done at ambient temp.

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                • #9
                  Re: The energy it takes to make biodiesel

                  Hi smithy,

                  Originally posted by smithy View Post
                  Maybe you should try a glyc wash Tilly, to reduce your costs.
                  People do not give me their methanol rich glycerol to perform a first stage reaction with.
                  In any event I only use 14% methanol in a single stage reaction and see no benefit in doing a 2 stage method.



                  BTW my glyc wash is also done at ambient temp.
                  Have you changed your mind again ??
                  On the infopop forum when I told a person he could do the first stage glycerine reaction without heating you objected saying:
                  "This doesn't work too well. As the reaction is what is known as an equilibrium reaction and even though there are excess chemicals in the glycerol, the reaction is too slow to proceed with any degree of practicality at ambient."

                  I have noticed that you frequently contradict something you have said in the past to disagree with something I have posted.
                  So are you now again doing both stages of your reaction for 45 minutes at room temperature

                  Comment


                  • #10
                    Re: The energy it takes to make biodiesel

                    Hi 3DB

                    Originally posted by 3DB View Post
                    Tony - I have reduced my start temp from 60C to 50C already to avoid excessive vaporisation of methanol. I mix for 90 min at present - do you think that is an overkill? I am keen to try 30C next batch.
                    The actual time it takes for the reaction to reach completion depends on a number of things including, but not limited to, the amount of chemicals used, the temperature of the reaction and mixing vigor of the reactor.
                    Some reactors are never able to achieve a complete reaction in a single stage and some are very quick.

                    You will need to do some testing to see how long it takes for your reactor to do a complete reaction.
                    I assume you want to make biodiesel that passes the 3/27 test and your reactor is currently making biodiesel that passes the 3/27 test in a 90 minute reaction at 60C.
                    You have now reduced the temperature to 50c and want to know how long it will take for your reactor to reach completion at this temperature.

                    This is what I would do in that situation.
                    Using the new reduced temperature, process a normal size batch of oil keeping all chemical quantities and production procedures normal except the new reduced temperature.
                    Every 10- 15 minutes remove a small sample from the reactor and allow it to sit for 5- 10 minutes which will allow some of the glycerine to settle out.
                    Then perform a 3/27 test from the sample taken.
                    Keep the reactor running until you have a pass on the 3/27 test.

                    While it is true there will be a small amount of methanol and glycerine remaining in the test biodiesel, this will give you a very good indication how your reaction is progressing and how long it will take for your reactor to achieve a complete reaction.

                    Please let us know what you find out.
                    tillyfromparadise
                    Senior Member
                    Last edited by tillyfromparadise; 26 September 2017, 03:48 PM.

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                    • #11
                      Re: The energy it takes to make biodiesel

                      Sounds like a good methodology, Tilly. Will do next batch.
                      3DB
                      1995 Holden (Isuzu) Rodeo 2.8TD 4X4 - B100 since April 2013
                      1976 Mercedes 300D Turbo 'The Coal Grenade' - B100 since May 2016 - SOLD
                      1994 Peugeot 405 SRDT 1.9L intercooled turbo diesel (Shitbox Rally car.) - B100 since August 2019 - SOLD
                      @thirddegreeburns on Instagram
                      @thirddegreeburns2019 on Facebook

                      Comment


                      • #12
                        Re: The energy it takes to make biodiesel

                        Hey Tilly,

                        Now that you have said it seems obvious. Cant believe I didn't think of such a simple thing before. 'face palm'.

                        I am upgrading to a more expensive car, and would like to investigate improvements to my process. the idea of monitoring the batch as it brews is a pearler.

                        Thankyou mate!

                        Comment


                        • #13
                          Re: The energy it takes to make biodiesel

                          Originally posted by 3DB View Post
                          Evening all,

                          Here's an electricity load profile of my house today while I made a batch of bio from 180L of WVO.

                          I try to get the whole operation as close to the middle of the day as I can while my 1.5 kW solar PV system is doing it's best.

                          As you can see, the PV barely touches the sides when the 2.4 kW oil heater is on, but it covers a lot of the mixer, which I run for 90 minutes to do the reaction.
                          I know there are quite a few electrical savvy people on this forum, so this is not aimed at those, but the rest of us knock about fixer-uppers. In QLD, im not sure about the other states, you can put up to 5.0Kw or thereabouts per phase down the line from solar production. Therefore if you have 3 phase at your house, you can upgrade to a 15.0kw system....

                          now this does require that you can access the additional funds, have lots of roof space for a big system and very little shading.

                          I recently fitted a 14kw system to my roof (52 solar panels with micro inverters) with what at the time was going to be a 5 year return on investment. I have just changed to Alita (or whatever its called) from red energy and have basically cut the ROI time in half. I now get 11.0c feed in tarrif as opposed to the 6.0c tarrif before and a big 25% discount for pay on time (which is easy because the bill is tiny) on I think 19 c/kwh as opposed to 26c /kwh.

                          Aircon can crank along all summer now. Very happy. I didnt know I could get such a big system until I chanced on a solar company that does large commercial installs. all the little operators that popped to service the domestic market just wanted to sell me a 5.0kw system.

                          Now I know this is a bit off topic, but it does lend a thought to the affordability of running bigger heaters to improve processes.

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                          • #14
                            Re: The energy it takes to make biodiesel

                            I did all the calcs years back on how much heat for how much oil for how long, I do know 1 joule per ml per degree C for water, just getthe specific heat of oil which is about 0.7 something and do some calcs.

                            Cade put in a 3 phase socket, and choose the heater element you want, 3 of, one per phase and go for it. If you really want I will put in a temp control,. automate the pump etc?Mine has a PID to get to 56, turnon the stirrer and I do some manual things, lots of work for ease of use!
                            Biodiesel Bandit

                            Landcruiser '98 80 series B100.

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                            • #15
                              Re: The energy it takes to make biodiesel

                              Cade - a 14kW domestic PV systems massive! You could probably put your washing machine, dishwasher, the AC and heat a batch of oil around midday and still be exporting to the grid. Good on you for offsetting the carbon emissions of many of your neighbours.

                              You will be well and truly set when the price of batteries gets to a reasonable level.

                              I would like to have more on my place, but it will be a struggle to fit much else. As it is, if I had batteries I would be self-sufficient 90% of the time, even with my little 1.5 kW system as we rarely use more than 4 kWh/day.
                              3DB
                              1995 Holden (Isuzu) Rodeo 2.8TD 4X4 - B100 since April 2013
                              1976 Mercedes 300D Turbo 'The Coal Grenade' - B100 since May 2016 - SOLD
                              1994 Peugeot 405 SRDT 1.9L intercooled turbo diesel (Shitbox Rally car.) - B100 since August 2019 - SOLD
                              @thirddegreeburns on Instagram
                              @thirddegreeburns2019 on Facebook

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